Fine Grained Cemented Carbide for Turning in Heat Resistant Super Alloys (HRSA)

ABSTRACT

Coated cemented carbide inserts, particularly useful in fine turning of super alloys, are disclosed. The inserts are characterized by a composition of a cemented carbide of WC, about 4.0 wt-% Co to about 7.0 wt-% Co, about 0.25 wt-% Cr to 0.50 wt-% Cr, and a coercivity (Hc) of about 28 kA/m to about 38 kA/m. The coating comprises a single (Ti 1-x Si x )N-layer, where x is between about 0.1 and about 0.25, with a crystal structure of NaCl type and a total thickness between about 0.5 μm and about 2.0 μm with a strong (200)-texture.

CROSS REFERENCE TO RELATED APPLICATIONS

This application claims priority to Swedish Application No. 0701702-3 filed Jul. 13, 2007, the entire disclosure of which is incorporated herein by reference.

FIELD OF THE INVENTION

The present invention relates to coated cutting tool inserts, which are particularly useful for turning of heat resistant super alloys. More specifically, the present invention relates to hard fine grained substrates in combination with a thin very hard adherent PVD-coating that greatly improve the wear resistance.

BACKGROUND OF THE INVENTION

Super alloys are a broad range of nickel, iron, and cobalt base alloys developed specifically for applications demanding exceptional mechanical and chemical properties at elevated temperatures. The classic use for these alloys is in the hot end of aircraft engines and land based turbines. Almost every metallurgical change made to improve the high temperature properties makes it more difficult to machine these alloys.

As high temperature strength is increased, the alloys become harder and stiffer at the cutting temperature. It results in increased cutting forces and increased wear on the cutting edge during machining.

Because stronger materials generate more heat during chip formation and because the thermal heat conductivity of these alloys is relatively low, very high cutting temperatures are generated, this also contribute to an increased wear of the cutting edge.

To make matters even worse, as the alloys are heat treated to modify the as cast or solution treated properties, abrasive carbide precipitates or other second phase particles often form. These particles do also cause rapid wear of the cutting edge.

EP 1174528 provides a multilayer-coated cutting tool. The first hard coating film is formed on the substrate and a second hard coating film formed on the first hard coating film. The first hard coating film comprises one or more of Ti, Al, and Cr, and one or more of N, B, C, and O. The second hard coating film comprises Si, and one or more metallic elements selected from the group consisting of metallic elements of Groups 4a, 5a and 6a of the Periodic Table and Al, and one or more non-metallic elements selected from the group consisting of N, B, C, and O.

WO 2006/118513 relates to a cutting tool insert, solid end mill, or drill, comprising a substrate and a coating. The coating is composed of a cubic C-(Me, Si) N-phase without coexisting amorphous phase. It is deposited by arc evaporation.

EP 1736565 relates to a cutting tool insert, solid end mill, or drill, comprising a substrate and a coating. The coating is composed of one or more layers of refractory compounds of which at least one layer comprises a cubic (Me,Si)X phase, where Me is one or more of the elements Ti, V, Cr, Zr, Nb, Mo, Hf, Ta and Al, and X is one or more of the elements N, C, O or B. The ratio R=(at-% X)/(at-% Me) of the c-MeSiX phase is between 0.5 and 1.0 and X contains less than 30 at-% of O+B.

US 2005/0019612 relates to a coated cutting tool made of cemented carbide with a hard coating layer, wherein (a) a crystal orientation hysteresis layer which consists of a carbonitride compound layer and (b) a hard coating layer which consists of a layer of nitride compound and has a well defined crystal orientation and/or degree of crystallinity are formed on the surface of a cemented carbide substrate, preferably on the surface of a tungsten carbide based cemented carbide or titanium carbonitride based cermet by physical vapor deposition, wherein the crystal orientation hysteresis layer is deposited between the surface of a cemented carbide substrate and the hard coating layer.

What is needed is a coated cemented carbide for fine wet turning of super alloys with improved wear resistance. The invention is directed to these, as well as other, important needs.

SUMMARY OF THE INVENTION

It has now surprisingly been found that a cemented carbide with low Co-content and submicron grain size coated with a single (Ti, Si)N-layer grown using physical vapor deposition greatly improves the productivity at fine turning of super alloys under wet conditions.

In one embodiment, the invention is directed to cutting tool inserts having a flank face, comprising:

a. a cemented carbide body having an edge radius, comprising:

-   -   tungsten carbide (WC);     -   about 4.0 wt-% to about 7.0 wt-% cobalt (Co);     -   about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and     -   wherein said cemented carbide body has a coercivity, Hc, of         about 28 kA/m to about 38 kA/m; and

b. a coating, comprising:

-   -   a single layer, comprising (Ti_(1-x)Si_(x))N, wherein x is         between about 0.1 and about 0.25;     -   wherein said layer has a crystal structure of NaCl type and a         total thickness between about 0.5 μm and 2.0 μm measured on the         middle of said flank face;     -   wherein said layer has a texture coefficient TC(200)>about 1.5,         the texture coefficient (TC) being defined as:

${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$

where:

-   -   I(hkl)=intensity of the (hkl) reflection;     -   I_(o)(hkl)=standard intensity according to JCPDS card no         38-1420;     -   n=number of reflections used in the calculation;     -   (hkl) reflections used are: (111), (200), and (220).

In another embodiment, the invention is directed to methods for making a cutting tool insert having a flank face, comprising a cemented carbide body and a coating, comprising the steps of:

-   -   providing a substrate made by conventional powder metallurgical         methods milling, pressing, and sintering with a composition         comprising:         -   tungsten carbide (WC);         -   about 4.0 wt-% to about 7.0 wt-% cobalt (Co);         -   about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and     -   wherein said composition has a coercivity, Hc, of about 28 kA/m         to about 38 kA/m; and     -   depositing a single layer, comprising (Ti_(1-x)Si_(x))N, wherein         x is between about 0.1 and about 0.25;     -   wherein said layer has a crystal structure of NaCl type and a         total thickness between about 0.5 μm and about 2.0 μm, measured         on the middle of said flank face;     -   wherein said layer has a texture coefficient TC(200)>about 1.5,         the texture coefficient (TC) being defined as:

${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$

where:

-   -   I(hkl)=intensity of the (hkl) reflection;     -   I_(o)(hkl)=standard intensity according to JCPDS card no         38-1420;     -   n=number of reflections used in the calculation;     -   (hkl) reflections used are: (111), (200), and (220).

using arc evaporation of an alloyed, or Ti+Si composite cathode having a composition comprising:

-   -   about 60 at-% Ti to about 90 at-% Ti, and balance Si;

with an evaporation current of between about 50 A and about 200 A and a substrate bias of between about −10 V and about −150 V, and a deposition temperature of between about 400° C. and about 700° C., and grown in an Ar+N₂ atmosphere comprising about 0 vol-% Ar to about 50 vol-% Ar, at a total pressure of about 0.5 Pa to about 9.0 Pa.

In yet other embodiments, the invention is directed to methods for fine wet turning of a super alloy, comprising the steps of:

-   -   providing the insert described above;     -   wet cutting said super alloy with said insert at a cutting speed         of about 35 m/min to about 130 m/min, a cutting depth of about         0.1 mm to about 0.75 mm; and a feed of about 0.05 mm/rev to         about 0.25 mm/rev.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention. In the drawings:

FIG. 1 shows a fracture surface of a coated cemented carbide substrate according to the present invention in which:

-   -   1. Cemented carbide body.     -   2. Single layer of (Ti, Si)N

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to a coated cutting tool insert particularly useful for turning of heat resistant super alloys. Hard fine grained substrates in combination with a thin very hard adherent PVD-coating greatly improve the wear resistance. It has now surprisingly been found that a cemented carbide with low Co-content and submicron grain size coated with a single (Ti, Si)N-layer grown using physical vapor deposition greatly improves the productivity at fine turning of super alloys under wet conditions.

In one embodiment, the invention is directed to cutting tool inserts having a flank face, comprising:

a. a cemented carbide body having an edge radius, comprising:

-   -   tungsten carbide (WC);     -   about 4.0 wt-% to about 7.0 wt-% cobalt (Co);     -   about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and     -   wherein said cemented carbide body has a coercivity, Hc, of         about 28 kA/m to about 38 kA/m; and

b. a coating, comprising:

-   -   a single layer, comprising (Ti_(1-x)Si_(x))N, wherein x is         between about 0.1 and about 0.25;     -   wherein said layer has a crystal structure of NaCl type and a         total thickness between about 0.5 μm and 2.0 μm measured on the         middle of said flank face;     -   wherein said layer has a texture coefficient TC(200)>about 1.5,         the texture coefficient (TC) being defined as:

${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$

where:

-   -   I(hkl)=intensity of the (hkl) reflection;     -   I_(o)(hkl)=standard intensity according to JCPDS card no         38-1420;     -   n=number of reflections used in the calculation;     -   (hkl) reflections used are: (111), (200), and (220).

According to the present invention there is now provided a coated cutting tool insert consisting of a substrate and a coating. The substrate consists of WC, about 4.0-7.0 wt-% Co, preferably about 4.5-6.0 wt-% Co, most preferably about 4.8-5.2 wt-% Co, about 0.25-0.50 wt-% Cr, preferably about 0.30-0.45 wt-% Cr, most preferably about 0.34-0.40 wt-% Cr and a coercivity (Hc) of about 28-38 kA/m, preferably about 30-36 kA/m, preferably about 31-34 kA/m. Preferably the edge radius of the inserts before coating is between about 0 and about 25 μm.

The coating consists of a single layer of (Ti_(1-x)Si_(x))N, where x is between about 0.1 and about 0.25, preferably between about 0. 12 and about 0.23, most preferably between about 0.18 and about 0.21. The crystal structure of the (Ti, Si)N-layer is of NaCl type. The total thickness of the layer is between about 0.5 and about 2.0 μm, preferably between about 0.7 and about 1.5 μm. The thickness is measured on the middle of the flank face.

The layer may contain Al in such an amount that in (Ti_(1-a-b)Si_(a)Al_(b))N, b≦a, about 0.1≦a≦about 0.25 and about 0.10≦a+b≦about 0.30.

The layer is strongly textured in the (200)-direction, with a texture coefficient of: TC(200)>about 1.5, preferably>about 2.0, most preferably>about 2.2.

The texture coefficient (TC) is defined as follows:

${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$

where:

-   -   I(hkl)=intensity of the (hkl) reflection;     -   I_(o)(hkl)=standard intensity according to JCPDS card no         38-1420;     -   n=number of reflections used in the calculation;     -   (hkl) reflections used are: (111), (200), and (220).

In another embodiment, the invention is directed to methods for making a cutting tool insert having a flank face, comprising a cemented carbide body and a coating, comprising the steps of:

-   -   providing a substrate made by conventional powder metallurgical         methods milling, pressing, and sintering with a composition         comprising:         -   tungsten carbide (WC);         -   about 4.0 wt-% to about 7.0 wt-% cobalt (Co);         -   about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and     -   wherein said composition has a coercivity, Hc, of about 28 kA/m         to about 38 kA/m; and     -   depositing a single layer, comprising (Ti_(1-x)Si_(x))N, wherein         x is between about 0.1 and about 0.25;     -   wherein said layer has a crystal structure of NaCl type and a         total thickness between about 0.5 μm and about 2.0 μm, measured         on the middle of said flank face;     -   wherein said layer has a texture coefficient TC(200)>about 1.5,         the texture coefficient (TC) being defined as:

${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$

where:

-   -   I(hkl)=intensity of the (hkl) reflection;     -   I_(o)(hkl)=standard intensity according to JCPDS card no         38-1420;     -   n=number of reflections used in the calculation;     -   (hkl) reflections used are: (111), (200), and (220).

using arc evaporation of an alloyed, or Ti+Si composite cathode having a composition comprising:

-   -   about 60 at-% Ti to about 90 at-% Ti, and balance Si;

with an evaporation current of between about 50 A and about 200 A and a substrate bias of between about −10 V and about −150 V, and a deposition temperature of between about 400° C. and about 700° C., and grown in an Ar+N₂ atmosphere comprising about 0 vol-% Ar to about 50 vol-% Ar, at a total pressure of about 0.5 Pa to about 9.0 Pa.

The present invention also relates to a method of making a coated cutting tool insert consisting of a substrate and a coating. The substrate is made by conventional powder metallurgical methods of milling, pressing, and sintering. It has a composition of WC, about 4.0-7.0 wt-% Co, preferably about 4.5-6.0 wt-% Co, most preferably about 4.8-5.2 wt-% Co, about 0.25-0.50 wt-% Cr, preferably about 0.30-0.45 wt-% Cr, most preferably about 0.34-0.40 wt-% Cr and a coercivity (Hc) of about 28-38 kA/m, preferably about 30-35 kA/m, most preferably about 31-32 kA/m.

Before coating the inserts are edge-honed by wet-blasting to an edge radius of preferably about 0 and about 25 μm.

The method used to grow the layer comprising (Ti,Si)N phase, is based on arc evaporation of an alloyed, or composite cathode, under the following conditions: The Ti+Si cathode composition is about 60 to about 90 at-% Ti, preferably about 70 to about 90 at-% Ti, and balance Si.

Before coating the surface is cleaned preferably by applying a soft ion etching. The ion etching is performed in an Ar atmosphere or in a mixture of Ar and H₂.

The evaporation current is between about 50 A and about 200 A depending on cathode size and cathode material. When using cathodes of 63 mm in diameter the evaporation current is preferably between about 60 A and about 120 A. The substrate bias is between about −10 V and about −150 V, preferably between about −40 V and about −70 V. The deposition temperature is between about 400° C. and about 700° C., preferably between about 500° C. and about 700° C.

The (Ti,Si)N-layer is grown in an Ar+N₂ atmosphere consisting of about 0-50 vol-% Ar, preferably about 0-20 vol-% Ar, at a total pressure of about 0.5 Pa to about 9.0 Pa, preferably about 1.5 Pa to about 5.0 Pa.

If Al should be present in the layer the cathode should comprise Al to a suitable amount to obtain the desired composition.

In yet other embodiments, the invention is directed to methods for fine wet turning of a superalloy, comprising the steps of:

-   -   providing the insert described above;     -   wet cutting said super alloy with said insert at a cutting speed         of about 35 m/min to about 130 m/min, a cutting depth of about         0.1 mm to about 0.75 mm; and a feed of about 0.05 mm/rev to         about 0.25 mm/rev.

The present invention also relates to the use of inserts according to above for wet, fine turning of super alloys such as Inconel 718, Inconel 625, Nimonic 81, Waspaloy or Ti6Al4V, at a cutting speed of about 35-130 m/min, a cutting depth about 0.1-0.75 mm and a feed of about 0.05-0.25 mm/rev.

The present invention is further defined in the following Examples, in which all parts and percentages are by weight, unless otherwise stated. It should be understood that these examples, while indicating preferred embodiments of the invention, are given by way of illustration only. From the above discussion and these examples, one skilled in the art can ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.

EXAMPLES Example 1

Cemented carbide cutting tool insert of type CNMG120408-MF1 consisting of a substrate and a coating were prepared. The substrate was made by milling, pressing and sintering. The composition was 5 wt-% Co, 0.37 wt-% Cr and rest WC. The coercivity was 31.5 kA/m corresponding to average WC grain size of about 0.5 μm.

The inserts were wet-blasted to an edge radius of about 20-25 μm.

The coating was grown using arc evaporation of a Ti_(0.80)Si_(0.20) cathode, 63 mm in diameter. The deposition was carried out in a 99.995% pure N₂ atmosphere at a total pressure of 4.0 Pa, using a substrate bias of −110 V for 60 minutes. The deposition temperature was about 530° C. X-ray diffraction showed a strong (002)-texture with (TC)=2.3 and FIG. 1 shows a fracture surface of the insert.

Example 2

Coated inserts from Example 1 were tested with regard to wear resistance at the following conditions: As reference Seco CP200, a commonly used grade for the mentioned application, was used.

Work piece: Cylindrical bar Material: Inconel 718 Cutting speed: 70 m/min Feed: 0.2 mm/rev Depth of cut: 0.5 mm Remarks: Flood coolant

Results

The tool life criterion was the maximum time in cut in minutes at a cutting speed of 70 m/min giving a flank wear of 0.2 mm. The results are found in Table 1.

TABLE 1 Grade Time in cut [min] Invention 14.50 Seco CP200 10.25

This test shows that the inserts according to the invention achieve 40% longer tool life than Seco CP200.

Example 3

Coated inserts from Example 1 were tested with regard to wear resistance at the following conditions: Seco CP200 was used as reference.

Work piece: Cylindrical bar Material: Inconel 718 Cutting speed: 70, 90, 110 m/min Feed: 0.15 mm/rev Depth of cut: 0.5 mm Remarks: Flood coolant

Results

The time in minutes to a flank wear of 0.2 mm was measured at three different cutting speeds. The results are found in Table 2.

TABLE 2 Cutting speed 70 90 110 Invention 15.0 11.0 6.0 Seco CP200 10.5 7.0 4.5

This test shows that the inserts according to the invention increase productivity 30% compared to Seco CP200.

Example 4

Coated inserts from Example 1 were tested with regard to wear resistance at the following conditions: As references three grades from market leading competitors were used, all three grades intended for the application in question.

Work piece: Special shaft Material: Inconel 718 Cutting speed: 40, 110 m/min Feed: 0.20 mm/rev Depth of cut: 0.25 mm Remarks: Flood coolant

Results

Reference grades all machined one shaft at the maximum cutting speed of 40 m/min. The inserts according to the invention managed to machine one component at the cutting speed 110 m/min.

This test shows that the inserts according to the invention increase productivity and speed capability compared to the references.

When ranges are used herein for physical properties, such as molecular weight, or chemical properties, such as chemical formulae, all combinations and subcombinations of ranges specific embodiments therein are intended to be included.

The disclosures of each patent, patent application, and publication cited or described in this document are hereby incorporated herein by reference, in their entirety.

Those skilled in the art will appreciate that numerous changes and modifications can be made to the preferred embodiments of the invention and that such changes and modifications can be made without departing from the spirit of the invention. It is, therefore, intended that the appended claims cover all such equivalent variations as fall within the true spirit and scope of the invention. 

1. A cutting tool insert having a flank face, comprising: a. a cemented carbide body having an edge radius, comprising: tungsten carbide (WC); about 4.0 wt-% to about 7.0 wt-% cobalt (Co); about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and wherein said cemented carbide body has a coercivity, Hc, of about 28 kA/m to about 38 kA/m; and b. a coating, comprising: a single layer, comprising (Ti_(1-x)Si_(x))N, wherein x is between about 0.1 and about 0.25; wherein said layer has a crystal structure of NaCl type and a total thickness between about 0.5 μm and 2.0 μm measured on the middle of said flank face; wherein said layer has a texture coefficient TC(200)>about 1.5, the texture coefficient (TC) being defined as: ${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$ where: I(hkl)=intensity of the (hkl) reflection; I_(o)(hkl)=standard intensity according to JCPDS card no 38-1420; n=number of reflections used in the calculation; (hkl) reflections used are: (111), (200), and (220).
 2. A cutting tool insert of claim 1, wherein said Co is present at a level of about 4.5 wt-% to about 6.0 wt-%.
 3. A cutting tool insert of claim 1, wherein said Cr is present at a level of about 0.30 wt-% to about 0.45 wt-%.
 4. A cutting tool insert of claim 1, wherein said cemented carbide body has a coercivity, Hc, of about 30 kA/m to about 36 kA/m.
 5. A cutting tool insert of claim 1, wherein x is between about 0.12 and about 0.23.
 6. A cutting tool insert of claim 1, wherein said layer has a total thickness between about 0.7 μm and about 1.5 μm measured on the middle of the flank face.
 7. A cutting tool insert of claim 1, wherein said layer has a texture coefficient TC(200) of greater than about 2.0.
 8. A cutting tool insert of claim 1, wherein said layer further comprises Al; wherein said Al is present in said layer in the ratio of (Ti_(1-a-b)Si₃Al_(b))N; where: b≦a; about 0.1≦a≦about 0.25; and 0.10≦a+b≦about 0.30.
 9. A cutting tool insert of claim 1, wherein said edge radius of said body is between about 0 μm and about 25 μm.
 10. A method for making a cutting tool insert having a flank face, comprising a cemented carbide body and a coating, comprising the steps of: providing a substrate made by conventional powder metallurgical methods milling, pressing, and sintering with a composition comprising: tungsten carbide (WC); about 4.0 wt-% to about 7.0 wt-% cobalt (Co); about 0.25 wt-% to about 0.50 wt-% chromium (Cr); and wherein said composition has a coercivity, Hc, of about 28 kA/m to about 38 kA/m; and depositing a single layer, comprising (Ti_(1-x)Si_(x))N, wherein x is between about 0.1 and about 0.25; wherein said layer has a crystal structure of NaCl type and a total thickness between about 0.5 μm and about 2.0 μm, measured on the middle of said flank face; wherein said layer has a texture coefficient TC(200)>about 1.5, the texture coefficient (TC) being defined as: ${{TC}({hkl})} = {\frac{I({hkl})}{I_{0}({hkl})}\left\lbrack {\frac{1}{n}{\sum\limits_{n = 1}^{n}\frac{I({hkl})}{I_{0}({hkl})}}} \right\rbrack}^{- 1}$ where: I(hkl)=intensity of the (hkl) reflection; I_(o)(hkl)=standard intensity according to JCPDS card no 38-1420; n=number of reflections used in the calculation; (hkl) reflections used are: (111), (200), and (220). using arc evaporation of an alloyed, or Ti+Si composite cathode having a composition comprising: about 60 at-% Ti to about 90 at-% Ti, and balance Si; with an evaporation current of between about 50 A and about 200 A and a substrate bias of between about −10 V and about −150 V, and a deposition temperature of between about 400° C. and about 700° C., and grown in an Ar+N₂ atmosphere comprising about 0 vol-% Ar to about 50 vol-% Ar, at a total pressure of about 0.5 Pa to about 9.0 Pa.
 11. A method of claim 10, wherein said Co is present at a level of about 4.5 wt-% to about 6.0 wt-%.
 12. A method of claim 10, wherein said Cr is present at a level of about 0.30 wt-% to about 0.45 wt-%.
 13. A method of claim 10, wherein said cemented carbide body has a coercivity, Hc, of about 30 kA/m to about 36 kA/m.
 14. A method of claim 10, wherein x is between about 0.12 and about 0.23.
 15. A method of claim 10, wherein said layer has a total thickness between about 0.7 μm and about 1.5 μm, measured on the middle of the flank face.
 16. A method of claim 10, wherein said layer has a texture coefficient TC(200)>about 2.0.
 17. A method of claim 10, wherein said insert is edge-honed by wet-blasting to an edge radius of between about 0 μm and about 25 μm before said insert is coated.
 18. A method of claim 10, said alloyed, or Ti+Si composite cathode having a composition comprises about 70 at-% Ti to about 90 at-% Ti.
 19. A method of claim 10, wherein said substrate bias is between about −40 V and about −70 V.
 20. A method of claim 10, wherein said deposition temperature is between about 500° C. and about 700° C.
 21. A method of claim 10, wherein said Ar+N₂ atmosphere comprises about 0 vol-% Ar to about 20 vol-% Ar.
 22. A method of claim 10, wherein said total pressure is about 1.5 Pa to about 5.0 Pa.
 23. A method for fine wet turning of a superalloy, comprising the steps of: providing an insert of claim 1; wet cutting said superalloy with said insert at a cutting speed of about 35 m/min to about 130 m/min, a cutting depth of about 0.1 mm to about 0.75 mm; and a feed of about 0.05 mm/rev to about 0.25 mm/rev.
 24. A method of claim 23, wherein said superalloy is Inconel 718, Inconel 625, Nimonic 81, Waspaloy, Ti6Al4V, or a combination thereof. 